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If only I found this site before I started: 25 Ways to Tie a Scarf. This was actually written in the 1960's by Sears! I think every girl needs a print out of this cheat sheet! Look at how many different ways you can tie a scarf! My fav and one that I'll probably be trying soon is #19. I guess the first three doesn't count but I wanted to include it because these are the basics to start you off. You can view the previous link for detailed tying directions.
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These are actually only a few ways. Here are some links to more creative ways to tie a scarf.
How to Wear a Scarf with Style
Scarf Tying Guide
How to Make an Asset Out of an Accessory